High energy e-beam irradiation is promising to produce solid-state batteries. Gel polymer electrolytes deliver excellent electrochemical performances. LFP/Li pouch cells exhibit high safety. The in-situ polymerization is a promising technique for achieving industrial-scale production of solid-state lithium metal batteries (LMBs).
More impressively, high-energy e-beam can penetrate through aluminum-plastic film to induce polymerization, which directly leads to the transformation from the liquid-state pouch cell to the solid-state. The solid-state LFP/Li pouch cell exhibits excellent cycling performance with a capacity retention of 83% after 100 cycles at 60 °C.
After the irradiation of high-energy e-beam, the precursor solution transformed into the GPEs by cross-linking reaction at room temperature. Such GPEs exhibit considerable ionic conductivity (0.17 mS cm −1 at 27 °C), high lithium-ion transference number (0.76 at 27 °C) and wide electrochemical working window (5.4 V, vs Li/Li +).
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The obtained GPEs deliver satisfactory ionic conductivity (0.17 mS cm −1 at 27 °C), high lithium-ion transference number (0.76 at 27 °C) and good electrochemical stability (5.4 V, vs Li/Li +). The LiFePO 4 /Li (LFP/Li) batteries based on the GPEs achieve excellent cycling stability (85% retention after 270 cycles) and rate performance.
As can be seen from the Fig. 3 d, there is not obvious oxidation current before 5.4 V (vs Li/Li +), revealing that the GPE-4 film possesses excellent electrochemical stability and is potential to be applied to high-voltage LMBs , .
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Online Services Email ContactThe new factory of Hebei JingHong Electronics Co., Ltd. will be officially put into production in October 2022. Mainly produce FR4 sheet, 3240 epoxy sheet, Bakelite sheet, and 3026 phenolic …
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